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Atomic Perspectives Column

Measurement Techniques for Mercury: Which Approach Is Right for You?

September 1, 2011

The advantages and disadvantages of measuring mercury with cold vapor atomic absorption spectroscopy, cold vapor atomic fluorescence spectroscopy, and direct analysis by thermal decomposition are explained.

Hyphenated ICP-MS Techniques for Speciation Analysis

March 1, 2009

The authors discuss speciation analysis methods that enable scientists to identify and measure the quantities of one or more individual chemical species in a sample.

Wilhelm Conrad Röntgen and the Discovery of X-Rays

July 14, 2009

Volker Thomsen takes a look at the impact that the discovery of X-rays by Wilhelm Röntgen in 1895 has had on the world.

The Spectral Lines of Hydrogen

November 1, 2008

A short history of the early scientific developments related to the optical emission lines of hydrogen is presented. These were crucial to the development of the quantum theory. Balmer's empirical formula was an important milestone. Rydberg and others provided additional work, especially for higher atomic numbers. However, it remained for Bohr to provide the physical reasoning.

A Pragmatic Approach to Managing Interferences in ICP-MS

May 1, 2008

While inductively coupled plasma-mass spectrometry (ICP-MS) is capable of part-per-quadrillion (ppq) detection limits under ideal conditions, most applications do not require this level of sensitivity and do not justify the cost associated with achieving it. Practical sensitivity in ICP-MS is determined not by instrument signal-to-noise ratio, but rather by controlling interferences and matrix effects in real samples. Understanding the sources of these effects and their management is critical in determining the most practical way to achieve specific data quality objectives.

Innovations in Speciation Analysis Using HPLC with ICP-MS Detection

April 1, 2008

Speciation analysis has grown rapidly and has expanded to a variety of markets, including environmental, clinical, food, nutraceutical, and bioanalytical. This growth has resulted from the realization that knowing the total amount of an element does not always provide adequate information for assessing health and environmental effects, but knowing which form of the element is present presents a much more comprehensive picture.

Analysis of Flue gas Desulfurization Wasterwaters by ICP-MS

November 1, 2011

Wastewater from coal-fired power plants is linked to a wide range of environmental and human health concerns. Measuring low levels of toxic trace metals in these wastewaters is complicated, however, by high levels of interfering matrix elements. A new EPA method using ICP-MS addresses this analytical challenge.

Close Enough: The Value of Semiquantitative Analysis

May 1, 2011

Most analytical measurements performed by either inductively coupled plasma–optical emission spectrometry (ICP-OES) or ICP–mass spectrometry (MS) require accuracy and precision, which are essential for obtaining correct answers. However, all modern ICP-OES and ICP-MS instruments have the ability to perform semiquantitative analyses. This seems strange since accuracy is important, but semiquantitative analysis does have a role in analytical measurements. This article will explore why semiquantitative analysis is important and will look at various ways it can be performed and implemented.

Using ICP-MS and ICP-OES to Measure Trace Elemental Impurities in Pharmaceuticals in Compliance with Proposed Pharmacopeia Chapters

March 1, 2011

The USP proposes the use of analytical techniques capable of measuring impurities at the specified limits with optimal selectivity, sensitivity, simplicity, and robustness.

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