Which ML Model Performed the Best?
Out of the four models tested, the researchers determined that PLS-DA delivered the most consistent and robust results across test conditions. According to the study, although all models performed well when background influence was minimal, they struggled to correctly classify thin colorless plastic fragments, particularly those with a thickness under 0.1 mm, when set against complex organic or inorganic environmental backgrounds (1). These fragments were frequently misidentified as part of the natural surroundings, contributing to their oversight in pollution assessments.
Overcoming this issue required the team to use a two-stage classification model. The first stage broadly identified plastic types, while the second stage zeroes in on fragments that were initially misclassified, especially colorless plastics (1). This refined strategy achieved more than 99% classification accuracy across various environmental scenarios, representing a major advancement in field-based plastic identification.
What Was Unique About This Study?
One unique aspect to this study is that it covered a wide range of materials. These include 15 types of macroplastics, microplastics, and rubber compounds within both organic and inorganic environments (1). Under mixed and noisy spectral backgrounds, the optimized models were able to rapidly and reliably classify colored plastics and rubbers without the need for prior sample handling (1).
One notable finding was that polymer surface color, except for black, had little effect on model performance. However, as anticipated, background conditions played a substantial role in interfering with the accurate detection of colorless plastics (1). These insights further underscore the importance of tailored models that account for specific environmental interferences in practical applications (1).
Despite its promising results, the researchers acknowledge that further refinement is needed for their method. As an example, the influence of surface coatings, environmental contamination, and chemical additives on spectral readings has yet to be fully explored (1). The team suggests that future improvements could involve hyperspectral unmixing to resolve overlapping spectral features and enhance model precision (1). They also recommend broadening the training data set to include plastic samples from diverse geographical and environmental sources to boost model generalizability (1).
In summary, this study provides a robust, scalable, and non-invasive technique for the simultaneous identification of both colored and colorless plastics in real-world environments. The method proposed here addresses an important limitation in current detection methods, giving researchers something to build off of in future studies.
References
- Zou, H.-H.; He, P.-J.; Peng, W.; et al. Rapid Detection of Colored and Colorless Macro- and Microplastics in Complex Environment via Near-infrared Spectroscopy and Machine Learning. J. Environ. Sci. 2025, 147, 512–522. DOI: 10.1016/j.jes.2023.12.004
- Wetzel, W. Microplastics Found in Deepest Reaches of Central Indian Ocean. Spectroscopy. Available at: https://www.spectroscopyonline.com/view/microplastics-found-in-deepest-reaches-of-central-indian-ocean (accessed 2025-06-02).
- Wetzel, W. Quantifying Microplastics and Anthropogenic Particles in Marine and Aquatic Environments. Spectroscopy. Available at: https://www.spectroscopyonline.com/view/quantifying-microplastics-and-anthropogenic-particles-in-marine-and-aquatic-environments (accessed 2025-06-02).
- Wetzel, W. Measuring Microplastics in Remote and Pristine Environments. Spectroscopy. Available at: https://www.spectroscopyonline.com/view/measuring-microplastics-in-remote-and-pristine-environments (accessed 2025-06-02).