January 2025

A comprehensive understanding of aging phenomena and the resulting performance loss occurring in lithium-ion batteries (LIBs) is essential for ongoing improvement of the technology. The formation of a uniform solid electrolyte interphase (SEI) is of crucial importance for the performance, lifetime, and safety of LIBs. Transition metal dissolution (TMD), caused by degradation of the cathode, and subsequent TM deposition on the anode surface can deteriorate the protective properties of the SEI, possibly leading to reconstruction of the SEI and loss of active lithium. We explore this topic here.

In recent years, advances in X-ray optics and detectors have enabled the commercialization of laboratory μXRF spectrometers with spot sizes of ~3 to 30 μm that are suitable for routine imaging of element localization, which was previously only available with scanning electron microscopy (SEM-EDS). This new technique opens a variety of new μXRF applications in the food and agricultural sciences, which have the potential to provide researchers with valuable data that can enhance food safety, improve product consistency, and refine our understanding of the mechanisms of elemental uptake and homeostasis in agricultural crops. This month’s column takes a more detailed look at some of those application areas.

In this "Icons of Spectroscopy" column, executive editor Jerome Workman Jr. details how Van Zandt Williams from Perkin-Elmer Corporation and American Cyanamid, and Norman E. Wright from the Dow Chemical Company, have made significant contributions to the field of vibrational spectroscopy.

In the fourth installment of our review of infrared spectral interpretation, we will discuss the spectroscopy of hydrocarbons. We will look at the stretching and bending vibrations of methyl (CH3) and methylene (CH2) groups, how to distinguish them, and how to know whether one or both of these functional groups are present in a sample. We will also discuss aromatic hydrocarbons, specifically the C-H stretching and bending peaks of mono- and disubstituted benzene rings, and how to distinguish them.

To improve the robustness and accuracy of logistic regression identification method, a new Raman spectroscopy identification method was proposed that combines a distributionally robust optimization technique and fused lasso technique with logistic regression. Then, Raman spectroscopy was used to analyze two types of dairy products that were collected for anti-jamming identification testing to verify the effectiveness of the new method.

A recent study used Fourier transform mid-infrared (FT-IR) spectroscopy and machine learning (ML) algorithms to understand the mineral content in camel’s milk.