Brian C. Smith

Articles

The Infrared Spectra of Polymers, Part I: Introduction

July 01, 2021

Polymers contain practically every infrared functional group imaginable. Now that we understand infrared functional groups from previous articles, it is time to look at the spectra of polymers in greater detail.

Spectral Subtraction

May 01, 2021

Determining the components in a mixture can be a significant challenge in infrared spectroscopy, but spectral subtraction can help. We show the proper way to perform spectral subtraction, and the pitfalls to avoid.

The Grand Review I: Why Do Different Functional Groups Have Different Peak Positions?

November 01, 2020

Articles in this column have addressed five main areas: theory, functional groups containing the C-H bond, those containing the C-O bond, those with the C=O bond, and those with organic nitrogen compounds. Here, we review the concepts.

Organic Nitrogen Compounds VIII: Imides

March 01, 2020

Here, we continue our examination of the infrared (IR) spectra of organic nitrogen compounds with imides, which are a common chemical intermediate. IR can be used not only to identify imides, but also to distinguish between straight chain and cyclic imides. We explain how.