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Rear view of senior farmer standing in soybean field examining crop at sunset. | Image Credit: © Zoran Zeremski - stock.adobe.com

A new review article highlights how Explainable Artificial Intelligence (XAI) can enhance transparency, trust, and innovation in agricultural spectroscopy, paving the way for smarter and more sustainable food quality assessment.

Unsolved Problems in Spectroscopy, Part 4

This tutorial investigates the persistent issue of sample heterogeneity—chemical and physical—during spectroscopic analysis. Focus will be placed on understanding how spatial variation, surface texture, and particle interactions influence spectral features. Imaging spectroscopy, localized sampling strategies, and adaptive averaging algorithms will be reviewed as tools to manage this problem, as one of the remaining unsolved problems in spectroscopy.

E. Bright Wilson, Jr.

This Icons of Spectroscopy Series article features E. Bright Wilson, a pioneer of chemical physics. Wilson’s contributions to infrared, Raman, and microwave spectroscopy provided the theoretical and practical foundation for analyzing molecular structure and dynamics. As a revered professor at Harvard and coauthor of landmark texts, he mentored nearly 150 students and researchers, leaving a lasting legacy of scientific excellence and integrity.

Researchers from the U.S. Horticultural Research Laboratory’s Agricultural Research Service present a preliminary characterization of the citrus peel materials responsible for elevated high performance liquid chromatography-ultraviolet (HPLC-UV) chromatogram baselines from citrus peel extracts through the use of Fourier-transform infrared (FTIR) and proton-nuclear magnetic resonance (1H-NMR) spectroscopy.

Unsolved Problems in Spectroscopy - Part 1

Inter-instrument variability is a major obstacle in multivariate spectroscopic analysis, affecting the reliability and portability of calibration models. This tutorial addresses the theoretical and practical challenges of model transfer across instruments. It covers spectral variability sources—such as wavelength shifts, resolution differences, and line shape variations—and presents key standardization techniques including direct standardization (DS), piecewise direct standardization (PDS), and external parameter orthogonalization (EPO). We discuss the underlying mathematics of these approaches using matrix notation and highlight limitations that must be considered for reliable universal calibration.