X-ray Analysis

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Spectroscopy

This November, NASA's Mars Science Laboratory will be launched on a mission to Mars that will deploy a new rover, called "Curiosity." Curiosity will include several analytical instruments, including "CheMin," which uses X-ray diffraction (XRD) and also has limited X-ray fluorescence (XRF) capabilities.

Spectroscopy

Koen Janssens, professor of chemistry at the University of Antwerp (Belgium), uses synchrotron radiation-based X-ray fluorescence (XRF) to analyze historic works of art. In a recent study, he used various spectroscopic techniques, including several X-ray methods, to reveal the process by which the yellow paint in some of Vincent Van Gogh?s paintings darkened over time.

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Spectroscopy

X-ray fluorescence spectroscopy (XRF) provides sensitive analysis of the atomic composition of samples. The technique is particularly well-suited for analyzing the elemental range from sodium to uranium, which covers the majority of the metallic elements.

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Application Notebook

Building on more than 10 years of Micro-XRF experience, the Orbis spectrometer yields a system with excellent Micro-XRF capability while setting a new standard in analytical flexibility.

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Application Notebook

One of the most common product safety-related analytical tests in the pharmaceutical industry (often referred to as a Limit Test) is the quantification of heavy metals or inorganics in all materials within a pharmaceutical product.

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Spectroscopy

X-ray diffractometry (XRD) is an X-ray–based method for determining the crystal structure of a material. Because X-ray wavelengths are of roughly the same size as the interatomic spacings of a crystal, significant diffraction of the waves occurs.

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Spectroscopy

X-ray fluorescence spectroscopy (XRF) is one of the primary analytical tools used in the cement industry for a variety of related applications. The principle of XRF is relatively simple; a source directs X-rays onto the atoms of the sample, ejecting electrons from the inner electron shells.

Spectroscopy

The twentieth century saw the rise of several novel instrumental techniques based on the use of X-rays. Today, X-ray spectroscopy and diffractometry continue to prove their utility as advances in instrumentation produce new methods and enable new applications.

Spectroscopy

The "fundamental parameters" approach to calibration in X-ray fluorescence is unique because it is based upon the theoretical relationship between measured X-ray intensities and the concentrations of elements in the sample. This theoretical relationship is based upon X-ray physics and the measured values of fundamental atomic parameters in the X-ray region of the electromagnetic spectrum. In this tutorial, an introduction to the means of calibration is provided based upon a simplified instrument–sample geometry, thus eliminating some of the mathematical details of the traditional derivations.

Spectroscopy

This tutorial reviews the mathematical models for dealing with interelement effects in optical emission and X-ray fluorescence spectrochemical analysis. Line overlaps and matrix effect corrections are examined.