Infrared (IR) Spectroscopy

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In this article, tunable diode laser absorption spectroscopy (TDLAS) is used to measure ammonia leakage, where a new denoising method combining empirical mode decomposition with the Savitzky-Golay smoothing algorithm (EMD-SG) is proposed to improve the signal-to-noise ratio (SNR) of absorbance signals.

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We wrap up our discussion of the mid-infrared spectra of inorganic compounds by looking at the spectra of silicates, nitrates, and phosphates. We will see that silicates have complex surface chemistry, and that infrared spectroscopy can tell us something about this. We will note that, of the five families of inorganics examined, the wavenumber ranges for the polyatomic anion stretching peaks in several of these functional groups overlap. However, polyatomic anion bending vibration peaks can be used to distinguish the five types of inorganics studied.

Peter R. Griffiths

Spectroscopy is publishing a series of feature articles highlighting the lives and careers of the most influential spectroscopists over the past 100 years. These individuals were selected by our Editorial Advisory Board and team of editors to represent the leading figures in spectroscopy over the century. Our second featured Icon of Spectroscopy is Peter R. Griffiths.

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This column discusses the spectra of different inorganic functional groups, such as sulfates, carbonates, nitrates, silicates, and phosphates, with special attention being paid to the stretching and bending vibrations of the polyatomic anions in these compounds.