Raman Spectroscopy

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In this interview with Spectroscopy, renowned planetary spectroscopist Alian Wang of Washington University in St. Louis discusses the development of the Mars microbeam Raman spectrometer (MMRS), proposed to be part of science payload for the NASA-funded mission, Mars 2020. Wang discusses the challenges involved in making the instrument robust enough for operation in space, and highlights how data collected from over 18 years has advanced our understanding of the history of Mars.

What exactly is a "Raman image" and how is it rendered? The authors explain those points, and demonstrate the use of Raman imaging for the characterization of thin-film and ion-implanted silicon structures. High spectral resolution makes it possible to resolve or contrast the substrate silicon and polysilicon film in Raman images and thus aids in the chemical or physical differentiation of spectrally similar materials.

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Volker Deckert, the winner of the 2013 Charles Mann Award, is advancing the use of tip enhanced Raman spectroscopy (TERS) to push the lateral resolution of vibrational spectroscopy well below the Abbe limit, to achieve single-molecule sensitivity. Because the tip can be moved with sub-nanometer precision, structural information with unmatched spatial resolution can be achieved without the need of specific labels.

With improvements in instrumentation, Raman spectroscopy continues to expand its range of applications to diverse areas of materials analysis and research.

Micro-Raman spectroscopy has been used to depth-profile a waveguide produced by an ion-exchange reaction in a single crystal of a ferroelectric metal oxide, and to reveal the changes in chemical bonding and atomic structure that occur in this process.

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Part of a new podcast series presented in collaboration with the Federation of Analytical Chemistry and Spectroscopy Societies (FACSS), in connection with SciX 2012 ? the Great Scientific Exchange, the North American conference (39th Annual) of FACSS.

Raman spectroscopy is a non-destructive technique that requires little or no sample preparation. Participants in this forum are Tom Tague, of Bruker Optics, and Robert Chimenti, of B&W Tek.

Raman Crystallography

Polarization/orientation micro-Raman spectroscopy promises to be an important analytical tool to complement micro-X-ray diffraction.