Fluorescence

Scientists create a highly selective fluorescent probe, ICM-Hg, for real-time detection of mercury ions (Hg2+) in water, food samples, and live cells.

A new fluorescent probe designed and synthesized by researchers can effectively and selectively detect Al3+ ions through the coexistence of photo-induced electron transfer (PET) and twisted intramolecular charge transfer (TICT) mechanisms.

This interview with Young Jong Lee highlights the work he and his team have done to reinvent solvent absorption compensation (SAC), and the potential it has across multiple forms of spectroscopy.

Our annual review of new products for atomic and molecular spectroscopy, including details by category and highlights of overarching trends.

A new method based on singular value decomposition (SVD) applied to the denoising of the time-resolved spectral matrix (TRSM) made it possible to obtain kinetics data of the fluorescence band parameters of a 3-aminophthalimide spectrum in acetonitrile.

Accurately measuring and quantifying the perception of color is an ongoing challenge for scientists, but understanding spectroscopic techniques can help standardize color measurements.

A kinetic fluorimetric method was established for the determination of formaldehyde in synthetic water samples and laundry water by potassium bromate oxidation of rhodamine B.

The possible energy transfer modes between Yb3+ and Tm3+ ions were analyzed.

The relationship between the complexation amount of thorium (Th) and Suwannee River fulvic acid (SRFA) and the changes in Th concentration and pH were studied using differential spectroscopy and 3D excitation-emission matrix fluorescence spectroscopy (3D EEM).

Förster resonance energy transfer (FRET) is a versatile part of the toolbox of fluorescence methods. This through-space, photon-less energy transfer process between a donor fluorophore and an acceptor chromophore is perhaps most famous for its utility as a “molecular ruler” that can resolve nanometer-scale distances. FRET is also a popular and advantageous basis for biomolecular assays and sensors.

A simple colorimetric and fluorescent dual-channel chemosensor was designed and synthesized to identify Hg2+ in an aqueous solution with demonstrated high selectivity and sensitivity.

Time-resolved fluorescence spectroscopy reveals much about the structure-induced energy transfer mechanisms of phycobilisomes, the light-harvesting antenna in cyanobacteria.

Help for handling sample-specific concerns in spectrofluorometry.

In the second part of a three-part series, instrument-specific concerns that require modifications to reproduce fluorescence spectra accurately are addressed.

A novel hydrazone-based CN- fluorescent probe, HNT, is described here, and a study was done to see if it could show selective recognition of CN- ions.

Analysts using fluorescence emission and fluorescence excitation spectroscopy may encounter several common problems in their measurements. This tutorial, the first of a three-part series, provides a procedure to help avoid them.

Here, a series of developing methods is presented for locating and analyzing deeply buried late Pleistocene archaeological sites, which includes the initial investigation of the geomorphology of a potential archaeological site with a suite of analytical geochemical techniques.

Phosphogypsum can be used as an intermediary material to produce cement clinker. To monitor the quality of phosphogypsum cement, a novel molecular layer deposition X-ray fluorescence (XRF) analysis method using a glass frit was developed.

The “selective fluorescence quenching effects” of Fe3+ ions on carbon dots are examined to gain a more comprehensive understanding of the interactions of metal ions with a variety of fluorescent materials.

Tunable narrowband light sources are essential for measuring fluorescence, reaction energetics, and other challenging measurements in chemical, biological, and physical systems. In particular, the optical parametric oscillator (OPO) is an indispensable tool.

Chemistry can help us understand the past.