All News


This is Chemometrics in Spectroscopy Column Number 251. In Column Number 250, we left you with a puzzle. We had just shown that a little-known piece of two-hundred-year-old mathematics, Lagrange's method of undetermined multipliers, could force an MLR calibration to ignore one particular, carefully chosen direction of repack-induced spectral change. It worked, but it only handled one direction at a time, and we admitted we had no idea whether the trick could be extended to PCR or PLS. That bothered us. So in this installment we go looking for the more general version of the idea, and we find it sitting in some very good recent work by Neal Gallagher and Nathanial Watson on what they call clutter suppression (a framework built for a completely different problem, target detection in hyperspectral imaging, that turns out to fit ours almost perfectly). Put the two together and you get an algorithm that whitens the calibration spectra with a clutter covariance matrix estimated from repack replicates, then hands the whitened data to the same Lagrangian machine we built last time. The payoff: the correction now generalizes to several, non-proportional directions of diffuse-reflection variability at once, and, because it is just a preprocessing step, it works ahead of PLS and PCR as well as MLR, which finally answers the question we could not answer before. This approach may very well be an answer to repack variation in repeated solid or slurry sample measurements using diffuse reflection. In this column we change gears with our writing tone and format by taking a "chemometry" approach, rather than a strict tutorial one. In future columns we hope to "unpack" this information in our more typical extended and tutorial manner. Let's explore solving this repack variation problem together.

Luxury red painted sports car © adel-chronicles-stock.adobe.com

A forensic case study using FT-IR, portable Raman spectroscopy, and SEM-EDS to differentiate three-layer automotive coatings from a hit-and-run accident, demonstrating that combining complementary spectroscopic and elemental techniques improves the accuracy of paint evidence identification.

A study using fiber laser induced breakdown spectroscopy (FL-LIBS) to evaluate how pulse width and repetition rate affect the quantitative analysis of elements in aluminum alloys, reporting improved detection sensitivity and limit of detection at high repetition rate.

Spectroscopy Top 10 DOI Articles of the Month (July 2026)

Spectroscopy Top 10 Articles of the Month (July 2026)

Published: | Updated:

The following articles are the most accessed digital object identifier (DOI) manuscripts for Spectroscopy and LCGC International during the month of July 2026. Nine articles are ranked here by DOI page views; a tenth entry in the July report (135 views) was recorded against the bare journal-level DOI rather than an individual article and is therefore not attributable to a single manuscript.